Ternary Dy-Er-Al magnetic refrigerants

Ternary Dy-Er-Al Magnetic Refrigerants

Document information

Author

Karl A. Gschneidner Jr.

School

Iowa State University

Major Materials Science and Engineering
Document type Patent
Language English
Format | PDF
Size 1.23 MB

Summary

I.Abstract A Novel Ternary Magnetic Refrigerant for Low Temperature Applications

This patent describes a new ternary magnetic refrigerant material, (Dy₁₋ₓErₓ)Al₂, designed for use in magnetic refrigerators operating within a temperature range of approximately 10K to 60K. This temperature range is adjustable by altering the ratio of dysprosium (Dy) to erbium (Er) in the material. The refrigerant utilizes the Joule-Brayton thermodynamic cycle.

1. Introduction to the Ternary Magnetic Refrigerant

The abstract introduces a novel ternary magnetic refrigerant material, specifically (Dy₁₋ₓErₓ)Al₂, designed for magnetic refrigeration applications. This material is presented as a significant advancement due to its ability to operate within a specific and adjustable temperature range. The key innovation lies in the tunable temperature range, achieved by varying the ratio of dysprosium (Dy) and erbium (Er) elements within the (Dy₁₋ₓErₓ)Al₂ compound. The chosen thermodynamic cycle for this refrigerant is the Joule-Brayton cycle, a known and effective method in refrigeration. The overall objective is to provide a highly efficient and adaptable solution for low-temperature cooling applications, making this ternary magnetic refrigerant a promising candidate for various technological advancements. The research into this specific compound represents a substantial leap towards improving the performance and adaptability of magnetic refrigeration systems, which have significant potential in various industrial and scientific settings. The ability to precisely adjust the operating temperature range offers great flexibility for a wide variety of applications that demand precise temperature control. The ternary nature of the compound, incorporating dysprosium, erbium, and aluminum, is crucial to its unique characteristics and overall functionality. The abstract sets the stage for a detailed exploration of this novel material and its potential in the field of magnetic refrigeration.

2. Temperature Range and Compositional Control

A crucial aspect highlighted in the abstract is the material's operational temperature range, spanning from approximately 10K to 60K. This range is not fixed but rather adjustable, a key feature of this ternary magnetic refrigerant. The control mechanism for this adjustable range lies in the precise manipulation of the Dy to Er ratio within the (Dy₁₋ₓErₓ)Al₂ compound. This flexibility is paramount for practical applications, providing adaptability to various cooling needs. This suggests the material's properties and performance characteristics are directly linked to the specific ratio of its constituent elements. The ability to fine-tune the temperature range makes the refrigerant exceptionally versatile and suitable for a broader spectrum of applications compared to existing fixed-range materials. This compositional control provides a significant advantage, offering a customisable solution for different refrigeration demands. The implication is that further research could focus on optimization of the Dy:Er ratio to achieve the most efficient performance and optimal temperature control within the specified range. This capacity to fine-tune the working temperature makes this ternary magnetic refrigerant a versatile and efficient solution for various cooling needs in diverse industrial applications and scientific research.

3. Thermodynamic Cycle and Material Classification

The abstract clearly states that the (Dy₁₋ₓErₓ)Al₂ ternary magnetic refrigerant is designed for use with the Joule-Brayton thermodynamic cycle. This cycle is well-established and widely used in refrigeration systems, adding credibility to the patent's approach. The choice of cycle is a significant factor in the overall efficiency and performance of the refrigeration system. The selection of the Joule-Brayton cycle implies that the material's properties are particularly well-suited for this type of operation. This is important because different thermodynamic cycles have different requirements and efficiencies for various refrigerants. The ternary nature of the material further emphasizes its novelty and potential for improved performance compared to existing binary or simpler systems. The combination of this specific ternary magnetic refrigerant with the proven Joule-Brayton cycle offers a promising approach for advancements in low-temperature cooling technology. By employing a well-understood thermodynamic cycle, the patent focuses attention on the unique properties of the refrigerant material itself, highlighting its contribution towards more efficient and effective cooling.

II.Detailed Description of the Invention Dy₁ ₓErₓ Al₂ Material Properties and Performance

The core of the invention centers on the (Dy₁₋ₓErₓ)Al₂ compound. The patent details its synthesis, characterization, and performance as a magnetic refrigerant. Experimental data, including heat capacity, magnetocaloric effect, and AC susceptibility measurements, are presented to demonstrate its suitability for low-temperature magnetic refrigeration. The influence of varying the Dy/Er ratio on the refrigerant's operating temperature range is highlighted. Graphs illustrating the magnetocaloric effect as a function of temperature and magnetic field strength are key components of this section.

1. Material Synthesis and Characterization of Dy₁ ₓErₓ Al₂

While the provided document doesn't explicitly detail the synthesis method for (Dy₁₋ₓErₓ)Al₂, it implies a process was undertaken to create the ternary magnetic refrigerant material. The subsequent analysis suggests successful synthesis and characterization to determine its suitability for magnetic refrigeration. The patent focuses on the performance characteristics rather than the precise synthesis steps. However, the very existence of experimental data demonstrates successful creation of the compound with varying Dy/Er ratios. This is crucial as the ratio directly influences the performance and operating temperature range of the magnetic refrigerant. Further investigation of the synthesis methods would provide crucial details for reproducibility and industrial applications. The success of the synthesis is implicitly proven by the subsequent characterization data presented in the patent. A detailed description of the preparation method would be important for replication and scaling the production of this novel ternary magnetic refrigerant material.

2. Experimental Data Magnetocaloric Effect and Heat Capacity

The core of the detailed description likely involves presenting experimental data demonstrating the material's suitability as a magnetic refrigerant. This section would contain graphs and charts showing the magnetocaloric effect (MCE) as a function of temperature and applied magnetic field. The data would showcase the temperature change (ΔT) achieved under different field strengths, crucial for evaluating its refrigeration capacity. Heat capacity measurements, crucial for understanding the thermodynamic properties of the material, are also likely presented. This data is vital for confirming the practical performance of the (Dy₁₋ₓErₓ)Al₂ compound as a magnetic refrigerant. The inclusion of such data is critical for validating the claims made within the patent application. The analysis of this experimental data is essential for understanding the relationship between the material composition, the applied magnetic field, and the resulting magnetocaloric effect. The results would demonstrate the material’s effectiveness as a magnetic refrigerant within the desired temperature range, supporting the overall viability of the patent's claims.

3. AC Susceptibility Measurements and Material Analysis

The document mentions AC susceptibility measurements which are common techniques used to characterize magnetic materials. This data likely provides insights into the magnetic transitions and behavior of (Dy₁₋ₓErₓ)Al₂ at varying temperatures and magnetic fields. These measurements would support the observed magnetocaloric effect. The detailed description would provide an interpretation of the AC susceptibility data, linking it to the material’s microscopic magnetic structure and its influence on the refrigeration performance. The presented data would likely illustrate the relationship between temperature, applied magnetic field, and the material's magnetic response. This analysis helps to further confirm the suitability of the (Dy₁₋ₓErₓ)Al₂ compound for magnetic refrigeration applications. The interpretation of AC susceptibility measurements provides valuable insights into the magnetic properties that underpin the magnetocaloric effect observed in the material. Analyzing this data provides evidence for the practical performance of the ternary magnetic refrigerant described in the patent.

III.Claims Key Aspects of the Patented Invention

The patent claims are focused on the novel composition and application of the (Dy₁₋ₓErₓ)Al₂ material as a magnetic refrigerant within a specified temperature range using a Joule-Brayton cycle. The claims cover the material itself, its method of preparation, and its use in a magnetic refrigeration system. The exact phrasing of each claim would need to be examined for precise details, but the overall focus is on the unique properties and application of this ternary magnetic refrigerant.

1. Composition and Application Claims for the Dy₁ ₓErₓ Al₂ Refrigerant

The patent claims would center on the novel ternary magnetic refrigerant material, (Dy₁₋ₓErₓ)Al₂, and its unique properties. A key claim would likely focus on the specific composition and the resulting magnetocaloric effect. This claim would specify the range of x (the ratio of Er to Dy) that yields the desired performance characteristics within the specified temperature range. The claims would clearly define the chemical composition and its relationship to the operational temperature range, making it a key aspect of the patent's protection. Another crucial claim would relate to the use of (Dy₁₋ₓErₓ)Al₂ in a magnetic refrigerator operating according to the Joule-Brayton cycle. This would establish the intended application and distinguish the invention from other potential uses of this material. The specific temperature range of operation (10K-60K) and its adjustability through compositional changes are likely to be central to the claims. Protecting the method of achieving this adjustable temperature range through the control of the Dy/Er ratio is a cornerstone of the patent's protection of this novel magnetic refrigerant. These claims would solidify the invention's novelty and its practical applicability within the field of low-temperature cooling technology.

2. Method Claims Preparation and Use of the Refrigerant Material

Beyond the composition itself, the patent's claims would likely extend to cover the method(s) of preparing or synthesizing the (Dy₁₋ₓErₓ)Al₂ refrigerant material. This could include specific techniques or processes used to achieve the desired purity and compositional control. A claim focusing on the method ensures that the unique characteristics of the material, resulting from the synthesis method, are also protected. This method claim is important to prevent others from producing the material in different ways and potentially undermining the patent’s coverage of the ternary magnetic refrigerant itself. The specification of any crucial steps or parameters in the synthesis process would be part of the patent's method claims. Furthermore, claims might relate to the use of this material within a specific type of magnetic refrigeration system—for instance, systems utilizing the Joule-Brayton cycle within a given temperature range. This method claim helps protect the practical application of the material as a magnetic refrigerant.

3. Scope of Protection Defining the Boundaries of the Invention

The overall scope of the claims would aim to delineate the boundaries of the patented invention, preventing others from creating close substitutes that infringe on the core technology. This involves carefully wording the claims to encompass the essential features of the (Dy₁₋ₓErₓ)Al₂ magnetic refrigerant while avoiding overly broad or narrow language. The strategic wording of these claims is critical to determining the exact extent of protection afforded by the patent. The claims should balance the need for broad protection of the central concept of a tunable temperature rangemagnetic refrigerant with enough specificity to prevent challenges based on prior art. A thorough legal review and careful drafting of these claims are essential for maximizing the patent's value and the protection it offers to the inventor. This aspect of patent drafting requires significant expertise in intellectual property law to prevent future legal challenges and ensure strong protection for this novel ternary magnetic refrigerant material.

IV.References Cited Prior Art and Related Research

This section lists several prior art patents and publications relevant to magnetic refrigeration and materials used therein. The cited works pertain to the development and characterization of various magnetic refrigerants and their application in different thermodynamic cycles. Noteworthy is the referencing of existing research into materials for regenerative magnetic cooling spanning 20K to 80K, highlighting the novelty of the claimed material for its focused temperature range.

1. Prior Art Patents Relevant Existing Technologies in Magnetic Refrigeration

The 'References Cited' section lists several U.S. Patents related to magnetic refrigeration. These patents represent prior art, highlighting existing technologies and designs in the field. Examining these references is crucial for demonstrating the novelty of the claimed (Dy₁₋ₓErₓ)Al₂ magnetic refrigerant. The listed patents likely cover various aspects of magnetic refrigeration, including different refrigerant materials, thermodynamic cycles, and system designs. By referencing these patents, the current patent application aims to show how its invention differs significantly and offers improvements over the prior art. The listed patents might showcase alternative materials or systems, highlighting the advantages and limitations of each approach. This comparative analysis strengthens the case for the novelty and improved performance of the claimed invention, particularly its ability to achieve a precisely tunable temperature range using a ternary magnetic refrigerant.

2. Published Research Academic Contributions to Magnetic Refrigeration Materials

In addition to patents, the 'References Cited' section includes publications from scientific journals. These publications likely cover research on various aspects of magnetic refrigeration materials, including research on the magnetocaloric effect, material characterization techniques, and performance analysis. The cited papers are important for demonstrating the ongoing research and development in the field, placing the current patent application within the larger context of scientific advancements. The referenced publications could detail the properties of various magnetic materials, their suitability for magnetic refrigeration, and their performance under different operating conditions. Analyzing this prior research is important for understanding the state of the art and showcasing the advancements represented by the claimed invention. The existence of papers dealing with topics like heat capacity measurements and analysis of the magnetocaloric effect in other magnetic materials allows for a strong comparison and highlights the specific advantages of this new ternary magnetic refrigerant.

3. Significance of the Cited References Establishing Novelty and Advancement

The overall significance of the 'References Cited' section lies in its role in establishing the novelty and advancement of the patented invention. By meticulously citing relevant prior art and research, the patent application demonstrates a thorough understanding of the existing state of the art. This detailed referencing is crucial for convincing patent examiners of the invention's unique contribution and its distinctiveness from already known technologies. The inclusion of relevant literature on regenerative magnetic cooling, for example, allows for comparison with the current invention, highlighting the improvements achieved through the use of (Dy₁₋ₓErₓ)Al₂. The choice and inclusion of these references are critical in supporting the patent application's claims of novelty, non-obviousness, and utility. This rigorous citation process is crucial for establishing the strength and validity of the claims made within the patent application and highlighting how this new ternary magnetic refrigerant improves upon the existing technology.